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Corundum, Diamond, and PtS Metal–Organic Frameworks with a Difference: Self‐Assembly of a Unique Pair of 3‐Connecting D 2 d ‐Symmetric 3,3′,5,5′‐Tetrakis(4‐pyridyl)bimesityl
Author(s) -
Natarajan Ramalingam,
Savitha Govardhan,
Dominiak Paulina,
Wozniak Krzysztof,
Moorthy J. Narasimha
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200461625
Subject(s) - corundum , diamond , tetrahedron , ligand (biochemistry) , metal , twist , materials science , crystallography , chemistry , geometry , metallurgy , mathematics , biochemistry , receptor
A ligand with a twist : The coordination of distorted‐tetrahedral D 2 d ‐symmetric tetrapyridylbimesityl (tpb) with O h , T d , and D 4 h metal centers leads to metal–organic frameworks with unprecedented topologies related to those of corundum, diamond, and PtS, respectively (see picture).