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Liquid‐Crystalline Assembly from Rigid Wedge–Flexible Coil Diblock Molecules
Author(s) -
Kim JungKeun,
Hong MinKi,
Ahn JongHyun,
Lee Myongsoo
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200461623
Subject(s) - wedge (geometry) , supramolecular chemistry , lamellar structure , bilayer , crystallography , variety (cybernetics) , materials science , nanotechnology , chemistry , computer science , physics , membrane , optics , crystal structure , artificial intelligence , biochemistry
Shape sorting : The incorporation of a flexible coil of variable length into a rigid wedge‐shaped building block leads to the spontaneous formation of a rich variety of supramolecular structures. These include a bilayer lamellar structure with in‐plane hexagonally ordered perforations (see picture, R=(CH 2 ) 13 CH 3 ).