A Hexapentaene‐Extended Quinocumulene Cyclotrimerized to a Tricyclobutabenzene Derivative | Zendy

Kawase Takeshi | Zendy; Minami Yuichiro | Zendy; Nishigaki Naoki | Zendy; Okano Satoshi | Zendy; Kurata Hiroyuki | Zendy; Oda Masaji | Zendy

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A Hexapentaene‐Extended Quinocumulene Cyclotrimerized to a Tricyclobutabenzene Derivative

Author(s) -

Kawase Takeshi,

Minami Yuichiro,

Nishigaki Naoki,

Okano Satoshi,

Kurata Hiroyuki,

Oda Masaji

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200461608

Subject(s) - alternation (linguistics) , derivative (finance) , benzene , ideal (ethics) , ring (chemistry) , propeller , symmetry (geometry) , crystallography , stereochemistry , physics , chemistry , geometry , mathematics , engineering , philosophy , organic chemistry , law , marine engineering , political science , linguistics , financial economics , economics

Rings around rings : Cyclotrimerization of a hexapentaene‐extended quinocumulene led to the novel tricyclobutabenzene derivative shown. Its molecular structure reveals a considerably distorted propeller configuration that deviates largely from the ideal C 3 symmetry. Moderate bond alternation is evident in the central benzene ring.

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