A Reductive‐Aggregation Route to [Mn 12 O 12 (OMe) 2 (O 2 CPh) 16 (H 2 O) 2 ] 2−  Single‐Molecule Magnets Related to the [Mn 12 ] Family | Zendy

Tasiopoulos Anastasios J. | Zendy; Wernsdorfer Wolfgang | Zendy; Abboud Khalil A. | Zendy; Christou George | Zendy

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A Reductive‐Aggregation Route to [Mn 12 O 12 (OMe) 2 (O 2 CPh) 16 (H 2 O) 2 ] 2− Single‐Molecule Magnets Related to the [Mn 12 ] Family

Author(s) -

Tasiopoulos Anastasios J.,

Wernsdorfer Wolfgang,

Abboud Khalil A.,

Christou George

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200461551

Subject(s) - crystallography , physics , materials science , chemistry

Axes of power : Jahn–Teller isomerism (that is, Jahn–Teller distortion along different axes) accounts for the presence of both faster and slower relaxing magnetization dynamics of the title compound (see core structure; blue Mn, red O, gray C), which is a single‐molecule magnet (SMM). The new compound is a structural variant of the [Mn 12 ] family of SMMs and is prepared by a reductive aggregation of [MnO 4 ] − in a mixture of MeOH/PhCO 2 H.

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