Very Stable and Highly Regioselective Supported Ionic‐Liquid‐Phase (SILP) Catalysis: Continuous‐Flow Fixed‐Bed Hydroformylation of Propene | Zendy

Riisager Anders | Zendy; Fehrmann Rasmus | Zendy; Flicker Stephan | Zendy; van Hal Roy | Zendy; Haumann Marco | Zendy; Wasserscheid Peter | Zendy

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Very Stable and Highly Regioselective Supported Ionic‐Liquid‐Phase (SILP) Catalysis: Continuous‐Flow Fixed‐Bed Hydroformylation of Propene

Author(s) -

Riisager Anders,

Fehrmann Rasmus,

Flicker Stephan,

van Hal Roy,

Haumann Marco,

Wasserscheid Peter

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200461534

Subject(s) - hydroformylation , propene , ionic liquid , catalysis , regioselectivity , rhodium , chemistry , phase (matter) , ionic bonding , chemical engineering , organic chemistry , engineering , ion

The advantages of heterogeneous catalysis and transition‐metal catalysis in ionic liquids are combined in rhodium bisphosphine catalysts in an ionic‐liquid phase on a silica support. These active, regioselective, and highly stable catalysts were applied in a fixed‐bed reactor for the continuous‐flow gas‐phase hydroformylation of propene.

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