[(Tp) 8 (H 2 O) 6 Cu II  6 Fe III  8 (CN) 24 ] 4+ : A Cyanide‐Bridged Face‐Centered‐Cubic Cluster with Single‐Molecule‐Magnet Behavior | Zendy

Wang Shi | Zendy; Zuo JingLin | Zendy; Zhou HongCai | Zendy; Choi Hye Jin | Zendy; Ke Yanxiong | Zendy; Long Jeffrey R. | Zendy; You XiaoZeng | Zendy

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[(Tp) 8 (H 2 O) 6 Cu II 6 Fe III 8 (CN) 24 ] 4+ : A Cyanide‐Bridged Face‐Centered‐Cubic Cluster with Single‐Molecule‐Magnet Behavior

Author(s) -

Wang Shi,

Zuo JingLin,

Zhou HongCai,

Choi Hye Jin,

Ke Yanxiong,

Long Jeffrey R.,

You XiaoZeng

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200461515

Subject(s) - crystallography , boron , cluster (spacecraft) , magnetic anisotropy , materials science , chemistry , analytical chemistry (journal) , magnetization , physics , magnetic field , organic chemistry , quantum mechanics , computer science , programming language , chromatography

A box of magnetic tricks : By using the anionic precursor [(Tp)Fe(CN) 3 ] − (Tp − =hydrotris(pyrazolyl)borate), the title compound, which is a new face‐centered‐cubic cluster, has been synthesized (see structure; red Fe, turquoise Cu, orange B, gray C, blue N, dark red O). Magnetic studies show that it exhibits single‐molecule‐magnet behavior with substantial axial magnetic anisotropy ( D =−0.16 cm −1 ).

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