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An Unprecedented Bridging Phenoxyl Radical in Dicopper( II ) Complexes: Evidence for an S =3/2 Spin State
Author(s) -
Michel Fabien,
Torelli Stéphane,
Thomas Fabrice,
Duboc Carole,
Philouze Christian,
Belle Catherine,
Hamman Sylvain,
SaintAman Eric,
Pierre JeanLouis
Publication year - 2005
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200461462
Subject(s) - bridging (networking) , cooperativity , chemistry , bridging ligand , solvent , ferromagnetism , metal , computer science , physics , quantum mechanics , organic chemistry , computer network , biochemistry
Cooperativity between metal centers and a bridging radical ligand, reflected by ferromagnetic exchange coupling, was studied with the dicopper complex shown. The stability, and thus the reactivity of the complex, is finely tuned by both the nuclearity of the complex and the nature of the coordinating solvent X.