( Z )‐Bis(alkylzinc)imido‐1,2‐di(2‐pyridyl)ethene: Intramolecular Stabilization of a Bis(alkylzinc)imide | Zendy

Westerhausen Matthias | Zendy; Kneifel Alexander N. | Zendy; Kalisch Alexander | Zendy

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( Z )‐Bis(alkylzinc)imido‐1,2‐di(2‐pyridyl)ethene: Intramolecular Stabilization of a Bis(alkylzinc)imide

Author(s) -

Westerhausen Matthias,

Kneifel Alexander N.,

Kalisch Alexander

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200461356

Subject(s) - diethylzinc , intramolecular force , imide , chemistry , amine gas treating , solid state , medicinal chemistry , photochemistry , polymer chemistry , stereochemistry , crystallography , organic chemistry , enantioselective synthesis , catalysis

Able to be stable : The reaction of diethylzinc and bis(2‐pyridylmethyl)amine yields the title complex by C–C coupling and deamination reactions. This complex is dimeric in the solid state (see structure; orange Zn, blue N, gray C). The pyridyl substituents enable the formation of a rare example of a bis(alkylzinc)imide.

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