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An Oriented 1D Coordination/Organometallic Dimetallic Molecular Wire with AgPd Metal–Metal Bonds
Author(s) -
Braunstein Pierre,
Frison Céline,
OberbeckmannWinter Nicola,
Morise Xavier,
Messaoudi Abdelatif,
Bénard Marc,
Rohmer MarieMadeleine,
Welter Richard
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200461291
Subject(s) - covalent bond , zigzag , metal , crystallography , group 2 organometallic chemistry , solid state , chemistry , organometallic chemistry , metal ions in aqueous solution , materials science , stereochemistry , polymer chemistry , molecule , crystal structure , organic chemistry , geometry , mathematics
A subtle electronic balance between covalent and dative interactions involving coordinated phosphanyl iminolate ligands results in the formation of an oriented, 1 D coordination/organometallic heterodimetallic polymer with Pd–Ag interactions (shown as purple and green, respectively). In the solid‐state, the lipophilic aromatic rings of the infinite zigzag chains are all on one side of the planes of metal ions, which results in an unusual layered structure.