The Deposition of Metallopeptide‐Based Coordination Polymers on Graphite Substrates: Effects of Side‐Chain Functional Groups and Local Surface Structure | Zendy

Novokmet Slobodan | Zendy; Alam Mohammad S. | Zendy; Dremov Viatcheslav | Zendy; Heinemann Frank W. | Zendy; Müller Paul | Zendy; Alsfasser Ralf | Zendy

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The Deposition of Metallopeptide‐Based Coordination Polymers on Graphite Substrates: Effects of Side‐Chain Functional Groups and Local Surface Structure

Author(s) -

Novokmet Slobodan,

Alam Mohammad S.,

Dremov Viatcheslav,

Heinemann Frank W.,

Müller Paul,

Alsfasser Ralf

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200461274

Subject(s) - pyrolytic carbon , graphite , polymer , deposition (geology) , highly oriented pyrolytic graphite , crystallography , coordination polymer , surface (topology) , materials science , chemistry , crystal (programming language) , crystal structure , organic chemistry , geometry , pyrolysis , paleontology , mathematics , sediment , computer science , programming language , biology

The surface dictates : The metallodipeptide complex [{Zn(Dpg‐Tyr‐O)} n ] n + (Dpg=dipicolylglycyl, Tyr=tyrosine) is a right‐handed homochiral helical coordination polymer. Depending on the local structure of a pyrolytic graphite surface, it aggregates to form double‐helical plaits (left) or two‐dimensional assemblies of linearly stretched strands (right). The strands represent the first step in the formation of a three‐dimensional crystal.

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