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Highly Interpenetrated Metal–Organic Frameworks for Hydrogen Storage
Author(s) -
Kesanli Banu,
Cui Yong,
Smith Milton R.,
Bittner Edward W.,
Bockrath Bradley C.,
Lin Wenbin
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200461214
Subject(s) - metal organic framework , hydrogen storage , zinc , hydrogen , metal , chemical engineering , materials science , chemistry , polymer chemistry , computer science , organic chemistry , engineering , adsorption
Packing them in : Based on zinc and aromatic‐rich dicarboxylic acids these new coordination networks (see structure; green Cl, red O, yellow Zn, blue N, gray C) have hydrogen uptakes comparable to those of the best carbon nanotubes and metal–organic frameworks. The highly interpenetrating nature of these networks points to a new design strategy for hydrogen‐storage materials that employ an entrapment mechanism.

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