Premium
Alkyl Aluminum Halide Promoted Intramolecular Cyclization of ω ‐Allyl‐cycloalk‐2‐enones: Access to Bridged Bi‐ and Tricyclic Compounds
Author(s) -
Goeke Andreas,
Mertl Daniel,
Brunner Gerhard
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200461207
Subject(s) - tricyclic , intramolecular force , halide , chemistry , alkyl , medicinal chemistry , cationic polymerization , organic chemistry
Cyclization makes the scent : A rearrangement of ω ‐allyl cycloalkenones leads to structurally complex bi‐ and tricyclic ketones in good yields (see scheme). The method allows efficient access to an olfactorily interesting class of compounds.