z-logo
Premium
A Simple, One‐Step Procedure for the Formation of Chiral Metallamacrocycles
Author(s) -
Campbell Katie,
Johnson Charles A.,
McDonald Robert,
Ferguson Michael J.,
Haley Michael M.,
Tykwinski Rik R.
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200461139
Subject(s) - acetylide , platinum , yield (engineering) , chemistry , one step , simple (philosophy) , conjugated system , twist , ligand (biochemistry) , combinatorial chemistry , two step , stereochemistry , computational chemistry , mathematics , materials science , organic chemistry , chemical engineering , catalysis , geometry , engineering , metallurgy , philosophy , polymer , epistemology , receptor , biochemistry
A twist in the final stage : Chiral, conjugated metallamacrocycles can be formed in excellent yield in a single step from achiral precursors by ligand exchange between ( R , R )‐ or ( S , S )‐chiraphos and trans platinum acetylide complexes (see scheme).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here
Accelerating Research

Address

John Eccles House
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom