Solid‐State Structure and Temperature/Evacuation‐Induced Dehydration of Sodium Saccharinate 1.875 Hydrate | Zendy

Naumov Panče | Zendy; Jovanovski Gligor | Zendy; Grupče Orhideja | Zendy; Kaitner Branko | Zendy; Rae A. David | Zendy; Ng Seik Weng | Zendy

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Solid‐State Structure and Temperature/Evacuation‐Induced Dehydration of Sodium Saccharinate 1.875 Hydrate

Author(s) -

Naumov Panče,

Jovanovski Gligor,

Grupče Orhideja,

Kaitner Branko,

Rae A. David,

Ng Seik Weng

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200461043

Subject(s) - hydrate , dehydration , chemistry , sodium , crystallography , clathrate hydrate , inorganic chemistry , chemical engineering , organic chemistry , biochemistry , engineering

Sweet solution : The P 2 1 / n ( Z =64) structure of the commercial sweetener sodium saccharinate, which has an unusually large unit cell of 15.6 nm 3 , is an occupational and displacive modulation of an idealized C 2/ m ( Z =8) structure that results from a structural misfit. This determination (see picture) shows—after more than 150 years of use of the compound as a food additive—that it is better regarded as a 1.875 hydrate than a dihydrate.

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