Templating Open‐ and Closed‐Chain Structures around Metal Complexes of Macrocycles | Zendy

Heath Sarah L. | Zendy; Laye Rebecca H. | Zendy; Muryn Christopher A. | Zendy; Lima Nicola | Zendy; Sessoli Roberta | Zendy; Shaw Rachel | Zendy; Teat Simon J. | Zendy; Timco Grigore A. | Zendy; Winpenny Richard E. P. | Zendy

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Templating Open‐ and Closed‐Chain Structures around Metal Complexes of Macrocycles

Author(s) -

Heath Sarah L.,

Laye Rebecca H.,

Muryn Christopher A.,

Lima Nicola,

Sessoli Roberta,

Shaw Rachel,

Teat Simon J.,

Timco Grigore A.,

Winpenny Richard E. P.

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200461006

Subject(s) - crystallography , template , tetrahedron , chemistry , counterion , molecule , alkyl , materials science , stereochemistry , nanotechnology , ion , organic chemistry

Ringing the changes : Complexes of azamacrocycles were used for the template synthesis of extraordinary new cyclic and acyclic chromium–nickel chains, which include the “S”‐shaped cluster shown (see picture) obtained when a cyclen‐based template is used. The results suggest a new method for making sophisticated polymetallic architectures.

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