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Surface‐Confined Metalloporphyrin Oligomers
Author(s) -
Van Ryswyk Hal,
Moore Erin E.,
Joshi Neel S.,
Zeni Rebecca J.,
Eberspacher Todd A.,
Collman James P.
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460992
Subject(s) - oligomer , porphyrin , ligand (biochemistry) , electrochemistry , chemistry , denticity , photochemistry , crystallography , materials science , polymer chemistry , electrode , biochemistry , receptor , crystal structure
The modular assembly of metalloporphyrin oligomers through the stepwise addition of Ru–porphyrin units and a bidentate linking ligand (L, see graphic) onto a surface‐confined isonicotinate ligand is reported. Electrochemical measurements of the resulting oligomer show that electrons are transported along the length of its backbone.