Surface‐Confined Metalloporphyrin Oligomers | Zendy

Van Ryswyk Hal | Zendy; Moore Erin E. | Zendy; Joshi Neel S. | Zendy; Zeni Rebecca J. | Zendy; Eberspacher Todd A. | Zendy; Collman James P. | Zendy

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Surface‐Confined Metalloporphyrin Oligomers

Author(s) -

Van Ryswyk Hal,

Moore Erin E.,

Joshi Neel S.,

Zeni Rebecca J.,

Eberspacher Todd A.,

Collman James P.

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460992

Subject(s) - oligomer , porphyrin , ligand (biochemistry) , electrochemistry , chemistry , denticity , photochemistry , crystallography , materials science , polymer chemistry , electrode , biochemistry , receptor , crystal structure

The modular assembly of metalloporphyrin oligomers through the stepwise addition of Ru–porphyrin units and a bidentate linking ligand (L, see graphic) onto a surface‐confined isonicotinate ligand is reported. Electrochemical measurements of the resulting oligomer show that electrons are transported along the length of its backbone.

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