An Octahedral Rhodium Cluster with Six Phosphine and 12 Hydride Ligands and 10 Too Few Electrons | Zendy

Dyson Paul J. | Zendy; McIndoe J. Scott | Zendy

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An Octahedral Rhodium Cluster with Six Phosphine and 12 Hydride Ligands and 10 Too Few Electrons

Author(s) -

Dyson Paul J.,

McIndoe J. Scott

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460924

Subject(s) - phosphine , rhodium , cluster (spacecraft) , hydride , octahedron , crystallography , chemistry , halide , transition metal , electron , metal , inorganic chemistry , crystal structure , physics , organic chemistry , nuclear physics , computer science , programming language , catalysis

Six of one and half a dozen of the other: A late‐transition‐metal octahedral cluster [Rh 6 (P i Pr 3 ) 6 (μ‐H) 12 ] 2+ ( 1 ) with six phosphine ligands has been reported with a structure and electron count akin to that of early‐transition‐metal halide clusters, and provides a unique link between the two classes of cluster (see scheme). Cluster 1 is also decorated with 12 hydride ligands.

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