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Copper Complex Cation Templated Gadolinium( III )–Isophthalate Frameworks
Author(s) -
Zhou YouFu,
Jiang FeiLong,
Yuan DaQiang,
Wu BenLai,
Wang RuiHu,
Lin ZhengZhong,
Hong MaoChun
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460919
Subject(s) - crystallography , isophthalic acid , polyhedron , hydrothermal circulation , chemistry , copper , ion , gadolinium , combinatorics , chemical engineering , mathematics , organic chemistry , terephthalic acid , polyester , engineering
Ions in cages : Hydrothermal reactions give two novel 3D heterometallic frameworks, [{[Gd 4 (ip) 7 (H 2 O) 2 ][Cu(bpy) 2 ] 2 } n ] ( 1 , bpy=2,2′‐bipyridine, H 2 ip=isophthalic acid; see structure, space filling models: [Cu(bpy) 2 ], polyhedra: Gd) and [{Gd 3 Cu(ip) 5 (Hip)(bpy)} n ]⋅ n H 2 O ( 2 ). The structure of 1 consists of charged cages containing two encapsulated Cu I complex cations, whereas that of 2 contains charged cavities in which Cu II complex cations are bound.