Supramolecular Assemblies of Starlike and V‐Shaped PB–PEO Amphiphiles | Zendy

Xu Jun | Zendy; Zubarev Eugene R. | Zendy

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Supramolecular Assemblies of Starlike and V‐Shaped PB–PEO Amphiphiles

Author(s) -

Xu Jun,

Zubarev Eugene R.

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460906

Subject(s) - amphiphile , supramolecular chemistry , micelle , ethylene oxide , polybutadiene , self assembly , molecule , chemistry , polymer chemistry , amphiphilic molecule , copolymer , materials science , organic chemistry , polymer , aqueous solution

A star is born in the form of a polybutadiene–poly(ethylene oxide) amphiphile 1 . The molecule exhibits remarkable self‐assembly properties: it forms regular and reverse micelles in water and hexane, respectively. Comparison of 1 with a V‐shaped precursor revealed a profound influence of molecular architecture on the self‐assembly behavior of the amphiphiles.

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