A Palladium( II )‐Clipped Aromatic Sandwich | Zendy

Kumazawa Kazuhisa | Zendy; Yamanoi Yoshinori | Zendy; Yoshizawa Michito | Zendy; Kusukawa Takahiro | Zendy; Fujita Makoto | Zendy

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A Palladium( II )‐Clipped Aromatic Sandwich

Author(s) -

Kumazawa Kazuhisa,

Yamanoi Yoshinori,

Yoshizawa Michito,

Kusukawa Takahiro,

Fujita Makoto

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460868

Subject(s) - palladium , ligand (biochemistry) , distortion (music) , conjugated system , molecule , chemistry , composition (language) , materials science , crystallography , computer science , stereochemistry , polymer science , organic chemistry , polymer , telecommunications , art , literature , amplifier , biochemistry , receptor , catalysis , bandwidth (computing)

A filling that makes the sandwich : Large aromatic molecules are sandwiched by two π‐conjugated ligands (L) that are joined together by six {(en)Pd} 2+ units (M; en=1,2‐ethanediamine; see picture; guest red, {(en)Pd} 2+ yellow, ligand blue). This host has an M 6 L 2 composition and is distorted by the concave shape of the ligand. Without a guest, it releases the distortion by forming the dimeric M 12 L 4 in a reversible fashion.

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