Helical Chirality in Pentacoordinate Zinc Complexes—Selective Access to Both Pseudoenantiomers with One Ligand Configuration | Zendy

Seitz Michael | Zendy; Stempfhuber Sabine | Zendy; Zabel Manfred | Zendy; Schütz Martin | Zendy; Reiser Oliver | Zendy

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Helical Chirality in Pentacoordinate Zinc Complexes—Selective Access to Both Pseudoenantiomers with One Ligand Configuration

Author(s) -

Seitz Michael,

Stempfhuber Sabine,

Zabel Manfred,

Schütz Martin,

Reiser Oliver

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460843

Subject(s) - heteroatom , zinc , ligand (biochemistry) , chirality (physics) , chemistry , oxazoline , crystallography , stereochemistry , physics , organic chemistry , ring (chemistry) , quantum mechanics , biochemistry , chiral symmetry breaking , receptor , nambu–jona lasinio model , quark , catalysis

Δ 2 or Λ 2 , that is the question! Depending on the heteroatom X, the pentadentate bis(oxazoline) ligand will fold around a zinc( II ) ion exclusively in the Δ 2 or Λ 2 configuration, both in solution and in the solid state.

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