Catalytic Hydrohydrazination of a Wide Range of Alkenes with a Simple Mn Complex | Zendy

Waser Jérôme | Zendy; Carreira Erick M. | Zendy

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Catalytic Hydrohydrazination of a Wide Range of Alkenes with a Simple Mn Complex

Author(s) -

Waser Jérôme,

Carreira Erick M.

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460811

Subject(s) - catalysis , substrate (aquarium) , steric effects , scope (computer science) , chemistry , simple (philosophy) , reaction conditions , combinatorial chemistry , organic chemistry , computer science , philosophy , oceanography , programming language , geology , epistemology

Enhanced activity , lower catalyst loading, shorter reaction times, and expanded substrate scope are the advantages of [Mn(dpm) 3 ] over Co catalysts in the hydrohydrazination reaction of alkenes (see scheme). Thus, sterically hindered alkenes, including tetrasubstituted alkenes, can now also readily undergo this reaction.

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