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Spectroscopic Elucidation of a Peroxo Ni 2 (μ‐O 2 ) Intermediate Derived from a Nickel( I ) Complex and Dioxygen
Author(s) -
KieberEmmons Matthew T.,
Schenker Ralph,
Yap Glenn P. A.,
Brunold Thomas C.,
Riordan Charles G.
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460747
Subject(s) - nickel , dimer , hydroxide , chemistry , thermal decomposition , solvent , ligand (biochemistry) , hydrocarbon , coordination complex , inorganic chemistry , polymer chemistry , crystallography , metal , organic chemistry , biochemistry , receptor
O 2 for you : The trans ‐μ‐1,2‐peroxo Ni 2 dimer 3 , a structural motif unknown previously in nickel coordination chemistry, was produced by reaction of the (tmc)nickel( I ) precursor 1 with O 2 . Thermal decomposition of 3 in CH 3 CN leads to 2 , in which the atoms of the hydroxide ligand derive from O 2 and the hydrocarbon solvent.