Spectroscopic Elucidation of a Peroxo Ni 2 (μ‐O 2 ) Intermediate Derived from a Nickel( I ) Complex and Dioxygen | Zendy

KieberEmmons Matthew T. | Zendy; Schenker Ralph | Zendy; Yap Glenn P. A. | Zendy; Brunold Thomas C. | Zendy; Riordan Charles G. | Zendy

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Spectroscopic Elucidation of a Peroxo Ni 2 (μ‐O 2 ) Intermediate Derived from a Nickel( I ) Complex and Dioxygen

Author(s) -

KieberEmmons Matthew T.,

Schenker Ralph,

Yap Glenn P. A.,

Brunold Thomas C.,

Riordan Charles G.

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460747

Subject(s) - nickel , dimer , hydroxide , chemistry , thermal decomposition , solvent , ligand (biochemistry) , hydrocarbon , coordination complex , inorganic chemistry , polymer chemistry , crystallography , metal , organic chemistry , biochemistry , receptor

O 2 for you : The trans ‐μ‐1,2‐peroxo Ni 2 dimer 3 , a structural motif unknown previously in nickel coordination chemistry, was produced by reaction of the (tmc)nickel( I ) precursor 1 with O 2 . Thermal decomposition of 3 in CH 3 CN leads to 2 , in which the atoms of the hydroxide ligand derive from O 2 and the hydrocarbon solvent.

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