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Enantioselective Synthesis of Tetrafluoroethylene‐Containing Monosaccharides
Author(s) -
Boydell A. James,
Vinader Victoria,
Linclau Bruno
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460746
Subject(s) - enantioselective synthesis , monosaccharide , dihydroxylation , tetrafluoroethylene , sharpless asymmetric dihydroxylation , block (permutation group theory) , organic chemistry , chemistry , catalysis , mathematics , combinatorics , copolymer , polymer
A Sharpless asymmetric dihydroxylation of the commercially available building block 1 affords the common chiral intermediate 2 for the synthesis of the fluorinated monosaccharides 3 – 5 (Bn=benzyl).
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