Supramolecular Assembly of Luminescent Gold( I ) Alkynylcalix[4]crown‐6 Complexes with Planar η 2 ,η 2 ‐Coordinated Gold( I ) Centers | Zendy

Yip SungKong | Zendy; Cheng Eddie ChungChin | Zendy; Yuan LiHua | Zendy; Zhu Nianyong | Zendy; Yam Vivian WingWah | Zendy

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Supramolecular Assembly of Luminescent Gold( I ) Alkynylcalix[4]crown‐6 Complexes with Planar η 2 ,η 2 ‐Coordinated Gold( I ) Centers

Author(s) -

Yip SungKong,

Cheng Eddie ChungChin,

Yuan LiHua,

Zhu Nianyong,

Yam Vivian WingWah

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460744

Subject(s) - luminescence , excited state , planar , supramolecular chemistry , crystallography , materials science , nanotechnology , chemistry , optoelectronics , physics , crystal structure , atomic physics , computer science , computer graphics (images)

Au⋅⋅⋅Au interactions between the gold( I ) centers arranged in a planar rhomboidal array in a novel class of luminescent tetranuclear gold( I ) alkynylcalix[4]crown‐6 complexes (see picture) give rise to rich luminescence behavior, with long‐lived excited states and relatively high luminescence quantum yields.

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