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Rigid and Flexible: A Highly Porous Metal–Organic Framework with Unusual Guest‐Dependent Dynamic Behavior
Author(s) -
Dybtsev Danil N.,
Chun Hyungphil,
Kim Kimoon
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460712
Subject(s) - dabco , octane , sorption , porosity , metal organic framework , materials science , dimethylformamide , porous medium , metal , chemical engineering , chemistry , organic chemistry , adsorption , composite material , solvent , engineering , metallurgy
A large H 2 sorption capacity and high surface area are properties of the depicted metal–organic porous material, which is easily synthesized on a large scale from readily available chemicals. The rigid framework of [Zn 2 (1,4‐bdc) 2 (dabco)] (1,4‐H 2 bdc=1,4‐benzenedicarboxylic acid; dabco=diazabicyclo[2.2.2]octane) is also flexible enough to exhibit unusual guest‐dependent dynamic behavior, as shown (DMF= N,N ‐dimethylformamide).