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3,6‐Di(azido)‐1,2,4,5‐Tetrazine: A Precursor for the Preparation of Carbon Nanospheres and Nitrogen‐Rich Carbon Nitrides
Author(s) -
Huynh My Hang V.,
Hiskey Michael A.,
Archuleta Jose G.,
Roemer Edward L.,
Gilardi Richard
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460708
Subject(s) - tetrazine , carbon fibers , nitride , nitrogen , carbon nitride , chemistry , materials science , nanotechnology , organic chemistry , catalysis , composite material , layer (electronics) , photocatalysis , composite number
A high‐nitrogen compound , 3,6‐di(azido)‐1,2,4,5‐tetrazine, was used as precursor for the preparation of carbon nanospheres (see SEM picture) and nitrogen‐rich carbon nitrides. The conversions into both carbon‐based materials are simple, occur under mild conditions (low temperature, no applied pressure), and require no vacuum systems, extraction, carbonization, and purification.