Linear, Redox‐Active Pt 6  and Pt 2 Pd 2 Pt 2  Clusters | Zendy

Goto Eri | Zendy; Begum Rowshan A. | Zendy; Zhan Shuzhong | Zendy; Tanase Tomoaki | Zendy; Tanigaki Katsumi | Zendy; Sakai Ken | Zendy

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Linear, Redox‐Active Pt 6 and Pt 2 Pd 2 Pt 2 Clusters

Author(s) -

Goto Eri,

Begum Rowshan A.,

Zhan Shuzhong,

Tanase Tomoaki,

Tanigaki Katsumi,

Sakai Ken

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460707

Subject(s) - redox , platinum , metal , chemistry , crystallography , transition metal , materials science , inorganic chemistry , catalysis , organic chemistry

A piece of jewelry is the complex [Pt 4 M 2 (μ‐H)(μ‐dpmp) 4 (XylNC) 2 ](PF 6 ) 3 (M=Pt, see structure), which contains the longest platinum chain characterized so far. This complex and the related compound with M=Pd are redox‐active and can be readily oxidized to the electron‐deficient clusters [Pt 4 M 2 (μ‐dpmp) 4 (XylNC) 2 ](PF 6 ) 4 (M=Pt, Pd) with dynamic structural changes in the metal strings. Xyl=2,6‐dimethylphenyl, dpmp=bis(diphenylphosphanylmethyl)phenylphosphane.

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