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Self‐Assembly of Interpenetrating Coordination Nets Formed from Interpenetrating Cationic and Anionic Three‐Dimensional Diamondoid Cluster Coordination Polymers
Author(s) -
Liang Kai,
Zheng Hegen,
Song Yinglin,
Lappert Michael F.,
Li Yizhi,
Xin Xinquan,
Huang Zixiang,
Chen Jiutong,
Lu Shaofang
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460681
Subject(s) - diamondoid , cationic polymerization , cluster (spacecraft) , polymer , materials science , nonlinear optical , polymer science , computer science , polymer chemistry , nanotechnology , chemistry , nonlinear system , physics , molecule , computer network , organic chemistry , composite material , quantum mechanics
Tetrathiometalates [WS 4 ] 2− are the nodal building blocks in a new kind of heterometallic interpenetrating three‐dimensional cluster coordination polymer (see picture) that has interesting nonlinear optical properties. The polymer exhibits optical self‐focusing behavior and reverse saturable absorption effects.