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Kinetic Self‐Assembly: Selective Cross‐Catenation of Two Sterically Differentiated Pd II ‐Coordination Rings
Author(s) -
Hori Akiko,
Yamashita Kenichi,
Fujita Makoto
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460671
Subject(s) - catenation , steric effects , chemistry , coordination complex , kinetic energy , stereochemistry , crystallography , metal , organic chemistry , physics , quantum mechanics , dna , biochemistry
Magic rings : The trick of kinetically controlled cross‐catenation of two different Pd II ‐linked coordination rings (see picture) lies in the large difference in the catenation rate of the two rings as a result of steric hindrance of the ligands.
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