Photoconversion of a Redox‐Active Self‐Assembled Monolayer: In Situ Probing of Photoinduced CO Dissociation from a Triruthenium Cluster Center on Gold | Zendy

Abe Masaaki | Zendy; Masuda Takuya | Zendy; Kondo Toshihiro | Zendy; Uosaki Kohei | Zendy; Sasaki Yoichi | Zendy

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Photoconversion of a Redox‐Active Self‐Assembled Monolayer: In Situ Probing of Photoinduced CO Dissociation from a Triruthenium Cluster Center on Gold

Author(s) -

Abe Masaaki,

Masuda Takuya,

Kondo Toshihiro,

Uosaki Kohei,

Sasaki Yoichi

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460651

Subject(s) - photoexcitation , monolayer , photochemistry , dissociation (chemistry) , redox , chemistry , ruthenium , self assembled monolayer , cluster (spacecraft) , gold cluster , in situ , electrode , inorganic chemistry , catalysis , density functional theory , excited state , organic chemistry , computational chemistry , biochemistry , physics , computer science , nuclear physics , programming language

Photoresponsive self‐assembled monolayers (SAMs): Photoexcitation of a CO‐bearing trinuclear ruthenium cluster assembled on an Au(111) electrode results in dissociation of CO to form a H 2 O‐terminated SAM (see picture). This is the first well‐defined example of clean conversion of a redox‐active molecular film by using light stimulus.

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