Unusual Magnetic Metal–Cyanide Cubes of Re II  with Alternating Octahedral and Tetrahedral Corners | Zendy

Schelter Eric J. | Zendy; Prosvirin Andrey V. | Zendy; Reiff William M. | Zendy; Dunbar Kim R. | Zendy

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Unusual Magnetic Metal–Cyanide Cubes of Re II with Alternating Octahedral and Tetrahedral Corners

Author(s) -

Schelter Eric J.,

Prosvirin Andrey V.,

Reiff William M.,

Dunbar Kim R.

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460614

Subject(s) - triphos , octahedron , cyanide , crystallography , tetrahedron , divalent metal , chemistry , halide , metal , divalent , inorganic chemistry , crystal structure , organic chemistry

Two cyanide‐bridged molecular cubes of general formula [{MCl} 4 {Re II (triphos)(CN) 3 } 4 ], M=Fe, Co (depicted), triphos=1,1,1‐tris(diphenylphosphanylmethyl)ethane, and their magnetic properties are reported. The cubes are prepared in good yields from the reaction of the Re II complex [Et 4 N][Re II (triphos)(CN) 3 ] with the appropriate divalent metal halide and consist of octahedral Re II and tetrahedral M corners bridged by cyanide ligands.

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