A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction | Zendy

Férey Gérard | Zendy; Serre Christian | Zendy; MellotDraznieks Caroline | Zendy; Millange Franck | Zendy; Surblé Suzy | Zendy; Dutour Julien | Zendy; Margiolaki Irène | Zendy

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A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction

Author(s) -

Férey Gérard,

Serre Christian,

MellotDraznieks Caroline,

Millange Franck,

Surblé Suzy,

Dutour Julien,

Margiolaki Irène

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460592

Subject(s) - powder diffraction , diffraction , crystallography , association (psychology) , materials science , computer science , chemical engineering , chemistry , physics , engineering , optics , philosophy , epistemology

A perfect combination : The association of a chromium( III ) trimeric building unit and 1,3,5‐benzenetricarboxylate led to the powdered solid MIL‐100. Simulations provided a crystal structure solution, which matched the experimental powder XRD pattern. This unique simulation/diffraction combination allowed the structure determination of a giant‐pore solid with a zeotype architecture, built up from hybrid supertetrahedra (see picture).

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