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[{[Pt(en) 2 ][PtX 2 (en) 2 ]} 3 ][{(MX 5 )X 3 } 2 ]⋅12 H 2 O: Quasi‐One‐Dimensional Halogen‐Bridged Pt II –Pt IV Mixed‐Valence Compounds with Magnetic Counteranions
Author(s) -
Yamashita Masahiro,
Kawakami Daisuke,
Matsunaga Satoshi,
Nakayama Yoshio,
Sasaki Mari,
Takaishi Shinya,
Iwahori Fumiyasu,
Miyasaka Hitoshi,
Sugiura Kenichi,
Wada Yoshiki,
Miyamae Hiroshi,
Matsuzaki Hiroyuki,
Okamoto Hiroshi,
Tanaka Hisaaki,
Marumoto Kazuhiro,
Kuroda Shinichi
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460580
Subject(s) - chemistry , valence (chemistry) , crystallography , halogen , molecule , crystal structure , platinum , hexagonal crystal system , stereochemistry , catalysis , organic chemistry , alkyl
Attractive complexes : Hexagonal micropores similar to zeolites have been observed in mixed‐valence Pt II –Pt IV compounds with magnetic counteranions (see X‐ray crystal structure). The micropores contain 12 water molecules per molecular unit which can be desorbed by heating the complexes to 100 °C and re‐adsorbed by cooling to 20 °C without affecting the skeletal structure.