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The [NH 3 Cl] + Ion
Author(s) -
Schneider Stefan,
Haiges Ralf,
Schroer Thorsten,
Boatz Jerry,
Christe Karl O.
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460544
Subject(s) - chemistry , lewis acids and bases , ion , inorganic chemistry , polymer chemistry , organic chemistry , catalysis
Stable! The first stable salts containing a simple, inorganic cation with an NCl bond are prepared (see picture). They are [NH 3 Cl] + [BF 4 ] − , [NH 3 Cl] + [AsF 6 ] − , and [NH 3 Cl] + [SbF 6 ] − and can be safely prepared from (Me 3 Si) 2 NCl in mixtures of HF and the corresponding Lewis acids and could be used as storable generators for monochloramine gas.