[Yb 3 N(dpa) 6 ][Yb(dpa) 3 ]: A Molecular Nitride of a Rare‐Earth Metal with a Yb 3 N Unit | Zendy

Quitmann Catharina C. | Zendy; MüllerBuschbaum Klaus | Zendy

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[Yb 3 N(dpa) 6 ][Yb(dpa) 3 ]: A Molecular Nitride of a Rare‐Earth Metal with a Yb 3 N Unit

Author(s) -

Quitmann Catharina C.,

MüllerBuschbaum Klaus

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460478

Subject(s) - homoleptic , ytterbium , nitride , rare earth , deprotonation , metal , ammonia , materials science , chemistry , earth (classical element) , inorganic chemistry , crystallography , ion , nanotechnology , physics , mineralogy , metallurgy , doping , organic chemistry , optoelectronics , layer (electronics) , mathematical physics

Centered by a nitride ion: The oxidation of ytterbium with 2,2′‐dipyridylamine in liquid ammonia at low temperatures leads to the novel compound [Yb 3 N(dpa) 6 ][Yb(dpa) 3 ], which is unique among homoleptic dipyridylamides of the rare‐earth metals. The complete deprotonation of NH 3 provides the first molecular nitride of a rare‐earth metal with a Yb 3 N unit (see picture; C blue, N green, Yb silver).

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