Ru( II ) Tris(bipyridyl) Complexes with Six Oligonucleotide Arms as Precursors for the Generation of Supramolecular Assemblies | Zendy

Stewart Kristen M. | Zendy; Rojo Javier | Zendy; McLaughlin Larry W. | Zendy

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Ru( II ) Tris(bipyridyl) Complexes with Six Oligonucleotide Arms as Precursors for the Generation of Supramolecular Assemblies

Author(s) -

Stewart Kristen M.,

Rojo Javier,

McLaughlin Larry W.

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460399

Subject(s) - ruthenium , duplex (building) , oligonucleotide , tris , supramolecular chemistry , dna , chemistry , template , combinatorial chemistry , stereochemistry , crystallography , nanotechnology , biochemistry , materials science , catalysis , crystal structure

The 3D starshaped Ru–bpy–DNA complex pictured comprises a ruthenium( II ) tris(bipyridyl) center with six DNA 20‐mer sequences tethered through linkers at its 4‐ and 4′‐positions. The complexes 1 and 2 hybridize with six complementary 20‐mer strands to form duplex arms. Alternatively, the complementary DNA strands in 1 and 2 hybridize with each other to form larger nanoscale assemblies.

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