Tetranuclear Homo‐ and Heteroalumoxanes Containing Reactive Functional Groups: Syntheses and X‐ray Crystal Structures of [{[LAl(Me)](μ‐O)(MH 2 )} 2 ] | Zendy

Singh Sanjay | Zendy; Kumar S. Shravan | Zendy; Chandrasekhar Vadapalli | Zendy; Ahn HansJürgen | Zendy; Biadene Marianna | Zendy; Roesky Herbert W. | Zendy; Hosmane Narayan S. | Zendy; Noltemeyer Mathias | Zendy; Schmidt  HansGeorg | Zendy

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Tetranuclear Homo‐ and Heteroalumoxanes Containing Reactive Functional Groups: Syntheses and X‐ray Crystal Structures of [{[LAl(Me)](μ‐O)(MH 2 )} 2 ]

Author(s) -

Singh Sanjay,

Kumar S. Shravan,

Chandrasekhar Vadapalli,

Ahn HansJürgen,

Biadene Marianna,

Roesky Herbert W.,

Hosmane Narayan S.,

Noltemeyer Mathias,

Schmidt HansGeorg

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460395

Subject(s) - gallium , core (optical fiber) , congener , hydride , crystallography , crystal structure , aluminium , chemistry , x ray , stereochemistry , materials science , physics , organic chemistry , nuclear physics , composite material , hydrogen

A core with corners : The first alumoxane containing an {Al 4 O 2 } core as well as a gallium congener with an {Al 2 Ga 2 O 2 } core are prepared by the reaction of an organoaluminum monohydroxide with MH 3 ⋅NMe 3 (see formula; M=Al, Ga; Ar=2,6‐ i Pr 2 C 6 H 3 ). These compounds contain reactive hydride groups on the central M 2 O 2 rings and methyl groups on the terminal aluminum atoms.

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