A Covalent‐Chemistry Approach to Giant Macromolecules and Their Wetting Behavior on Solid Substrates | Zendy

Zhang Afang | Zendy; Barner Jörg | Zendy; Göessl Illdiko | Zendy; Rabe Jürgen P. | Zendy; Schlüter A. Dieter | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

A Covalent‐Chemistry Approach to Giant Macromolecules and Their Wetting Behavior on Solid Substrates

Author(s) -

Zhang Afang,

Barner Jörg,

Göessl Illdiko,

Rabe Jürgen P.,

Schlüter A. Dieter

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460390

Subject(s) - highly oriented pyrolytic graphite , pyrolytic carbon , wetting , polymer science , adsorption , macromolecule , graphite , polymer , solid surface , covalent bond , molecule , mica , chemistry , methacrylate , polymer chemistry , chemical engineering , materials science , nanotechnology , organic chemistry , copolymer , chemical physics , composite material , engineering , biochemistry , pyrolysis

Hair raising! Poly(methyl methacrylate) chains grown on a dendronized polymer (denpol) having repeat units with terminal 2‐bromoisobutyramide groups produce a hairy surface. When adsorbed on mica, MoS 2 , and highly oriented pyrolytic graphite, the hairy denpol molecules have a quasi two dimensional backbone conformation. The 50‐nm‐long hairs bend back on the MoS 2 (see image) and graphite substrates.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research