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Pentasupertetrahedral Clusters as Building Blocks for a Three‐Dimensional Sulfide Superlattice
Author(s) -
Zheng Nanfeng,
Bu Xianhui,
Feng Pingyun
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460386
Subject(s) - cluster (spacecraft) , superlattice , sulfide , series (stratigraphy) , crystallography , ion , materials science , computer science , chemistry , geology , optoelectronics , paleontology , operating system , metallurgy , organic chemistry
Highly mobile extra‐framework cations encapsulated in the 3D open‐framework architecture of ICF‐26 result in remarkably high ion conductivity. The framework is composed of Li 4 In 22 S 44 18− clusters, which represent the second member of a series of pentasupertetrahedral clusters P n. The P2 cluster reported here is the largest member of the P n series so far. In the crystal, each P2 cluster shares all four corners with adjacent P2 clusters (see picture).