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Polyazido High‐Nitrogen Compounds: Hydrazo‐ and Azo‐1,3,5‐triazine
Author(s) -
Huynh MyHang V.,
Hiskey Michael A.,
Hartline Ernest L.,
Montoya Dennis P.,
Gilardi Richard
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460366
Subject(s) - oxygen balance , detonation , chemistry , nitrogen , standard enthalpy of formation , oxygen , combustion , nitro , explosive material , volatility (finance) , detonation velocity , carbon fibers , ring (chemistry) , nitro compound , organic chemistry , materials science , alkyl , composite number , financial economics , economics , composite material
20 nitrogens and six carbons : The compounds 1 and 2 , demonstrate that hydrazo and azo linkages can be used to desensitize polyazido high‐nitrogen compounds and also decrease their volatility. The compound 2 has the highest experimentally measured heat of formation reported for energetic organic compounds (+2171 kJ mol −1 ).