Self‐Oxidation of a Phenolate Complex to a Bimetallic Stilbene Quinone | Zendy

van der Boom Milko E. | Zendy; Zubkov Tatiana | Zendy; Shukla Atindra D. | Zendy; Rybtchinski Boris | Zendy; Shimon Linda J. W | Zendy; Rozenberg Haim | Zendy; BenDavid Yehoshoa | Zendy; Milstein David | Zendy

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Self‐Oxidation of a Phenolate Complex to a Bimetallic Stilbene Quinone

Author(s) -

van der Boom Milko E.,

Zubkov Tatiana,

Shukla Atindra D.,

Rybtchinski Boris,

Shimon Linda J. W,

Rozenberg Haim,

BenDavid Yehoshoa,

Milstein David

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460360

Subject(s) - bimetallic strip , chemistry , hydride , aryl , bond cleavage , photochemistry , quinone , oxidation process , cleavage (geology) , oxygen atom , oxygen , catalysis , metal , combinatorial chemistry , molecule , stereochemistry , organic chemistry , materials science , chemical engineering , alkyl , fracture (geology) , composite material , engineering

Do‐it‐yourself oxidation : The Rh III complex 1 undergoes a self‐oxidative coupling process, in which the phenolate oxygen atom serves as the oxidant, to give 2 and the hydride complex 3 ( 2 : 3 =1:3). This reaction involves cleavage of a strong aryl–oxygen bond. X‐ray analysis of 2 reveals that the two quinonoid CO bonds are η 2 ‐coordinated to the metal centers.

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