Experimental Detection of Theoretically Predicted N 2 CO | Zendy

de Petris Giulia | Zendy; Cacace Fulvio | Zendy; Cipollini Romano | Zendy; Cartoni Antonella | Zendy; Rosi Marzio | Zendy; Troiani Anna | Zendy

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Experimental Detection of Theoretically Predicted N 2 CO

Author(s) -

de Petris Giulia,

Cacace Fulvio,

Cipollini Romano,

Cartoni Antonella,

Rosi Marzio,

Troiani Anna

Publication year - 2005

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460310

Subject(s) - metastability , reionization , molecule , ionization , mass spectrometry , ion , electron ionization , chemistry , gas phase , electron , analytical chemistry (journal) , chemical physics , atomic physics , materials science , physics , chromatography , organic chemistry , nuclear physics

The missing link in the 28‐electron family of open‐chain N 4 , N 2 CO, and C 2 O 2 molecules has been detected in the gas phase as an isolated, intact N 2 CO species, whose lifetime exceeds 0.8 μs. The new metastable molecule has been prepared by neutralization–reionization mass spectrometry of labeled N 2 CO + ions, which were generated in various N 2 /CO ionized mixtures (see picture).

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