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Kinetic Control over the Thermal Stability of the InH Bond: Synthesis and Characterization of Amido Indium Hydride Complexes
Author(s) -
Baker Robert J.,
Jones Cameron,
Junk Peter C.,
Kloth Marc
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460304
Subject(s) - steric effects , hydride , indium , thermal stability , chemistry , intermolecular force , electromagnetic shielding , stability (learning theory) , crystallography , stereochemistry , organic chemistry , molecule , materials science , computer science , metal , composite material , machine learning
High thermal stability is a characteristic feature of the depicted amido indium hydride complex (In red; hydride yellow), which is amongst the first to be synthesized and characterized. The stability arises from steric shielding of the InH bond, which frustrates the formation of the intermolecular InHIn bridges.