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Rhodizonate Metal Complexes with a 2D Chairlike M 6 Metal–Organic Framework: [M(C 6 O 6 )(bpym)(H 2 O)]⋅ n H 2 O
Author(s) -
Wang ChihChieh,
Kuo ChenTsung,
Chou PiTai,
Lee GeneHsiang
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460278
Subject(s) - metal , denticity , transition metal , chelation , chemistry , metal ions in aqueous solution , crystallography , metal organic framework , inorganic chemistry , materials science , organic chemistry , catalysis , adsorption
Two transition‐metal rhodizonate complexes, [M(C 6 O 6 )(bpym)(H 2 O)]⋅ n H 2 O (M=Cd, n =1; M=Mn, n =2; bpym=2,2′‐bipyrimidine), are reported. Both the rhodizonate and bpym ligands are bis‐bidentate ligands (see the Cd example depicted) which chelate the metal ions, thus forming a novel 2D chairlike M 6 metal–organic framework.
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