The Topotactic Conversion of a Novel Layered Silicate into a New Framework Zeolite | Zendy

Ikeda Takuji | Zendy; Akiyama Yoshikatsu | Zendy; Oumi Yasunori | Zendy; Kawai Akiko | Zendy; Mizukami Fujio | Zendy

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The Topotactic Conversion of a Novel Layered Silicate into a New Framework Zeolite

Author(s) -

Ikeda Takuji,

Akiyama Yoshikatsu,

Oumi Yasunori,

Kawai Akiko,

Mizukami Fujio

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460168

Subject(s) - silicate , zeolite , condensation , dehydration , molecule , ion , chemical engineering , materials science , mineralogy , chemistry , crystallography , physics , organic chemistry , thermodynamics , engineering , catalysis , biochemistry

High‐density silicate sheets made up of five‐membered rings with Me 4 NOH molecules and K + ions in the porelike interlayer space: This is the structure of the silicate PLS‐1. When PLS‐1 (left picture) was heated above 673 K under vacuum, the novel zeolite CDS‐1 (right picture) was obtained as the result of topotactic dehydration–condensation reactions. CDS‐1 is a pure silicate and thermally stable, and should therefore find a range of industrial uses.

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