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Synthesis and Structure of [Ag 26 In 18 S 36 Cl 6 (dppm) 10 (thf) 4 ][InCl 4 (thf)] 2 —A Combined Approach of Theory and Experiment
Author(s) -
Ahlrichs Reinhart,
Eichhöfer Andreas,
Fenske Dieter,
Hampe Oliver,
Kappes Manfred M.,
Nava Paola,
OlkowskaOetzel Jolanta
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460052
Subject(s) - denticity , cluster (spacecraft) , crystal structure , density functional theory , chemistry , crystallography , ionic bonding , methane , ion , computational chemistry , organic chemistry , computer science , programming language
Difficult to determine , the molecular structure of the ionic cluster [Ag 26 In 18 S 36 Cl 6 (dppm) 10 (thf) 4 ] 2+ [InCl 4 (thf) − ] 2 (see picture, dppm=bis(diphenylphosphanyl)methane) was independently resolved by theoretical (density functional theory) and experimental (single‐crystal XRD, FTMS) methods. The cluster was synthesized by the reaction of AgOOCPh and InCl 3 with S(SiMe 3 ) 2 in the presence of the bidentate phosphane dppm.