Synthesis and Structure of [Ag 26 In 18 S 36 Cl 6 (dppm) 10 (thf) 4 ][InCl 4 (thf)] 2 —A Combined Approach of Theory and Experiment | Zendy

Ahlrichs Reinhart | Zendy; Eichhöfer Andreas | Zendy; Fenske Dieter | Zendy; Hampe Oliver | Zendy; Kappes Manfred M. | Zendy; Nava Paola | Zendy; OlkowskaOetzel Jolanta | Zendy

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Synthesis and Structure of [Ag 26 In 18 S 36 Cl 6 (dppm) 10 (thf) 4 ][InCl 4 (thf)] 2 —A Combined Approach of Theory and Experiment

Author(s) -

Ahlrichs Reinhart,

Eichhöfer Andreas,

Fenske Dieter,

Hampe Oliver,

Kappes Manfred M.,

Nava Paola,

OlkowskaOetzel Jolanta

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200460052

Subject(s) - denticity , cluster (spacecraft) , crystal structure , density functional theory , chemistry , crystallography , ionic bonding , methane , ion , computational chemistry , organic chemistry , computer science , programming language

Difficult to determine , the molecular structure of the ionic cluster [Ag 26 In 18 S 36 Cl 6 (dppm) 10 (thf) 4 ] 2+ [InCl 4 (thf) − ] 2 (see picture, dppm=bis(diphenylphosphanyl)methane) was independently resolved by theoretical (density functional theory) and experimental (single‐crystal XRD, FTMS) methods. The cluster was synthesized by the reaction of AgOOCPh and InCl 3 with S(SiMe 3 ) 2 in the presence of the bidentate phosphane dppm.

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