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Readily Available Onio‐Substituted Methyleneiminium Salts: Single Precursors for a Variety of Aminocarbenes
Author(s) -
Conejero Salvador,
Canac Yves,
Tham Fook S.,
Bertrand Guy
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200460045
Subject(s) - iminium , deprotonation , chemistry , organic chemistry , substitution reaction , substitution (logic) , carbene , combinatorial chemistry , catalysis , ion , computer science , programming language
From amides to carbenes : Phosphonio‐substituted iminium salts are readily available from the corresponding amides in a one‐pot reaction. Deprotonation followed by substitution reactions affords a variety of transient and stable amino carbenes (see scheme).