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A Silver‐Catalyzed Intramolecular Amidation of Saturated CH Bonds
Author(s) -
Cui Yong,
He Chuan
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200454243
Subject(s) - intramolecular force , regioselectivity , stereospecificity , chemistry , catalysis , molecule , silver salts , nitrogen , polymer chemistry , medicinal chemistry , organic chemistry , combinatorial chemistry , stereochemistry
Opportunities with silver : A dinuclear silver( I ) compound was found to efficiently catalyze the intramolecular amidation of saturated CH bonds of carbamates and sulfamates (see scheme). This highly regioselective, stereospecific reaction offers a practical method for the construction of cyclic nitrogen‐containing organic molecules.