Preparation and Reactivity of 1,3,5,7‐Tetrakis[4‐(diacetoxyiodo)phenyl]adamantane, a Recyclable Hypervalent Iodine( III ) Reagent | Zendy

Tohma Hirofumi | Zendy; Maruyama Akinobu | Zendy; Maeda Akihisa | Zendy; Maegawa Tomohiro | Zendy; Dohi Toshifumi | Zendy; Shiro Motoo | Zendy; Morita Tetsuichiro | Zendy; Kita Yasuyuki | Zendy

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Preparation and Reactivity of 1,3,5,7‐Tetrakis[4‐(diacetoxyiodo)phenyl]adamantane, a Recyclable Hypervalent Iodine( III ) Reagent

Author(s) -

Tohma Hirofumi,

Maruyama Akinobu,

Maeda Akihisa,

Maegawa Tomohiro,

Dohi Toshifumi,

Shiro Motoo,

Morita Tetsuichiro,

Kita Yasuyuki

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200454234

Subject(s) - hypervalent molecule , iodine , chemistry , reagent , adamantane , reactivity (psychology) , iodine compounds , oxidative phosphorylation , medicinal chemistry , combinatorial chemistry , organic chemistry , biochemistry , medicine , alternative medicine , pathology

A wide range of oxidative reactions are mediated by novel, nonpolymeric, and recyclable hypervalent I III reagents (e.g. 2 ). In all cases, tetraiodide 1 was recovered nearly quantitatively in pure form after a simple workup. Reoxidation of 1 to 2 with m ‐chloroperbenzoic acid also proceeded quantitatively, without loss of oxidative activity.

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