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Preparation and Reactivity of 1,3,5,7‐Tetrakis[4‐(diacetoxyiodo)phenyl]adamantane, a Recyclable Hypervalent Iodine( III ) Reagent
Author(s) -
Tohma Hirofumi,
Maruyama Akinobu,
Maeda Akihisa,
Maegawa Tomohiro,
Dohi Toshifumi,
Shiro Motoo,
Morita Tetsuichiro,
Kita Yasuyuki
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200454234
Subject(s) - hypervalent molecule , iodine , chemistry , reagent , adamantane , reactivity (psychology) , iodine compounds , oxidative phosphorylation , medicinal chemistry , combinatorial chemistry , organic chemistry , biochemistry , medicine , alternative medicine , pathology
A wide range of oxidative reactions are mediated by novel, nonpolymeric, and recyclable hypervalent I III reagents (e.g. 2 ). In all cases, tetraiodide 1 was recovered nearly quantitatively in pure form after a simple workup. Reoxidation of 1 to 2 with m ‐chloroperbenzoic acid also proceeded quantitatively, without loss of oxidative activity.